Product ID:EMPTY CYLINDER/RESIDUE OF TRICHLOROMONOFLUOROMETHANE(CFC-11)
MSDS Date:03/01/1996
FSC:8120
NIIN:01-355-9763
MSDS Number: BYFNK

FEDERAL SPECIFICATIONS, PROMULGATED BY GSA

X
WASHINGTON, DC
US

Emergency Phone: 800-424-9300

Preparer: HMIS-VBA

Cage: 81348

NORTH AMERICAN CYLINDERS INC

UNKNOW WASHINGTON, DC US

Cage: 0FPR4

TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES/SKIN: MILD IRRITATION.
INHALATION: NARCOTIC EFFECTS, UNCONSCIOUSNESS, RAPID HEART BEAT,
ASPHYXIATION. INGESTION:IRRITATION. CHRONIC-SKIN DEFATTING, CARDIAC
EFFECTS. TARGET ORGANS: CNS, HEAR T.
Explanation of Carcinogenicity:NOT LISTED AS A CARCINOGEN BY NTP, IARC
OR OSHA
Effects of Overexposure:EYES/SKIN:IRRITATION. INHALATION:
ASPHYXIATION,CARDIAC ARRHYTHMIAS. INGESTION:IRRITATION TO GASTRIC
OR DIGESTIVE TRACTS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH HEART OR
RESPIRATORY DISORDERS MAY PROVE ESPECIALLY SUSCEPTIBLE.

First Aid:EYES/SKIN:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.IF
IRRITATION PERSISTS, SEE DOCTOR. INHALATION:REMOVE TO FRESH AIR.
GIVE OXYGEN/CPR IF NEEDED. DO NOT GIVE STIMULANTS. SEE DOCTOR.
INGESTION:IF LARGE QUANTITIES ARE INGESTED, GASTRIC EMPTYING MIGHT
BE RECOMMENDED, SEE DOCTOR IMMEDIATELY.

Flash Point:NON-FLAMMABLE
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.

Spill Release Procedures:VENTILATE ENCLOSED SPACES UNTIL GAS IS
DISPERSED. USE RESPIRATOR AND PROTECTIVE CLOTHING. ABSORB IN INERT
MATERIAL AND PLACE IN APPROPIATE DISPOSAL CONTAINER AND SEAL. FLUSH
AREA WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE AND USE WITH ADEQUATE
VENTILATION. NEVER USE IN A CLOSED OR CONFINED SPACE. STORE IN COOL
PLACE (<120F,49C).
Other Precautions:DO NOT BREATHE VAPORS. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING.

Respiratory Protection:NOT NEEDED IF CONCENTRATIONS ARE CONTROLLED. IF
TLV IS EXCEEDED USE NIOSH-APPROVED RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN.
Ventilation:MECHANICAL AND/OR LOCAL EXHAUST TO KEEP CONCENTRATION BELOW
TLV.
Protective Gloves:CLOTH-LINED RUBBER GLOVES.
Eye Protection:GOGGLES/FULL FACE SHIELD IF SPLASHING.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
THIS NSN IS FOR EMPTY CYLINDERS, HOWEVER, THERE MAY BE A LEFT OVER
RESIDUE OF CFC-11 IN THE CYLINDERS. FOR RELATED NSN FOR CFC-11, SEE
6830-01-355-9758 AND 683-01-355-9759. TIR SAYS:CYLINDER COMPRESSE D
GAS, TRICHOLOMONOFLUOROMETHANE. BUT IT SHOULD BE NOTED THAT
TRICHLOROMONOFLUOROMETHANE IS A LIQUID NOT A GAS!

HCC:N1
Boiling Pt:B.P. Text:74.9F,23.8C
Vapor Pres:694
Vapor Density:5.14
Spec Gravity:1.46
Evaporation Rate & Reference:0.4 (ETHER =1)
Solubility in Water:NEGLIGIBLE (.011%)
Appearance and Odor:COLORLESS LIQUID, VERY SLIGHT ETHEREAL TO ODORLESS.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CERTAIN ELASTOMETERS,ALKALI,ALKALINE EARTH METALS, POWDERED
ALUMINUM,ZINC,BERYLLIUM,SODIUM,POTASSIUM AND BARIUM.
Stability Condition to Avoid:EXTREMELY HOT METAL SURFACES OR OPEN
FLAMES.
Hazardous Decomposition Products:MAY DECOMPOSE TO FORM HIGHLY TOXIC AND
IRRITATING HYDROGEN CHLORIDE,HYDROGEN FLUORIDE AND TRACES OF
PHOSGENE.

Waste Disposal Methods:RETURN TO MANUFACTURER FOR RECYCLING. CONTACT
YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.